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529-28-2 - 2-Iodoanisole, 99% - 2-Methoxyiodobenzene - A10150 - Alfa Aesar

A10150 2-Iodoanisole, 99%

CAS-Nummer
529-28-2
Synonyme
2-Methoxyiodobenzene

Größe Preis ($) Menge Verfügbarkeit
25g 37,50
100g 91,20
500g 371,00
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2-Iodoanisole, 99%

MDL
MFCD00001039
EINECS
208-456-4

Chemische Eigenschaften

Formel
C7H7IO
Molmasse
234.04
Siedepunkt
240-242°
Flammpunkt
>110°(230°F)
Dichte
1.800
Brechungsindex
1.6220
Sensitivität
Light Sensitive
Löslichkeit
Miscible with alcohol, chloroform and diethyl ether. Insoluble in water.

Anwendungen

2-Iodoanisole has been used in palladium/copper-catalyzed synthesis of o-(1-alkynyl)anisoles.

Bemerkungen

Light Sensitive, store in dark. Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

Literaturverweise

Dawei Yue et. al.Synthesis of 2,3-disubstituted benzo[b]furans by the palladium-catalyzed coupling of o-iodoanisoles and terminal alkynes, followed by electrophilic cyclization. Journal of Organic Chemistry. 2005, 70 (25), 10292-10296 .

Adam Morel et. al. Palladium-catalyzed asymmetric Heck arylation of 2,3-dihydrofuran--effect of prolinate salts. Dalton Transactions. 2013, 42 (4), 1215-1222.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P312a-P321-P332+P313-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,5028
Beilstein
1860243
Harmonized Tariff Code
2909.30
TSCA
Yes

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