Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

540-51-2 - 2-Bromoethanol, 97% - Ethylene bromohydrin - 2-Hydroxyethyl bromide - A10275 - Alfa Aesar

A10275 2-Bromoethanol, 97%

CAS-Nummer
540-51-2
Synonyme
Ethylene bromohydrin
2-Hydroxyethyl bromide

Größe Preis ($) Menge Verfügbarkeit
25g 23,59
250g 109,18
1000g 337,84
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

2-Bromoethanol, 97%

MDL
MFCD00002827
EINECS
208-748-1

Chemische Eigenschaften

Formel
C2H5BrO
Molmasse
124.97
Schmelzpunkt
-80°
Siedepunkt
149-150°
Flammpunkt
>110°(230°F)
Dichte
1.762
Brechungsindex
1.4930
Sensitivität
Light Sensitive & Hygroscopic
Löslichkeit
Miscible with water, organic solvent and petroleum ether.

Anwendungen

2-Bromoethanol is utilized in selective reduction of nitroarenes. It is used as a solvent and organic synthetic raw material. It finds application in the synthesis of 2-piperidin-1-yl-ethanol by reacting with piperidine. It is used in selective reduction of nitroarenes.

Bemerkungen

Light sensitive. Hygroscopic. Store in a cool place. Incompatible with strong acids, strong oxidizing agents, strong reducing agents, acid chlorides and acid anhydrides.

Literaturverweise

Carboxylic acids protected as their 2-bromoethyl esters are readily deprotected by cleavage with sodium trithiocarbonate: Synthesis, 715 (1974). 2-Bromoethyl esters of amino acids have been cleaved by conversion with NaI (Finkelstein) to the corresponding iodo esters, followed by reductive cleavage with Zn in DMF: Chem. Ber., 112, 2145 (1979); Angew. Chem. Int. Ed., 20, 894 (1981). See also Appendix 6.

Bao, J.; Tranmer, G. K. The utilization of copper flow reactors in organic synthesis. Chem. Commun. 2015, 51 (15), 3037-3044.

Davis, O. A.; Croft, R. A.; Bull, J. A. Synthesis of diversely functionalised 2, 2-disubstituted oxetanes: fragment motifs in new chemical space. Chem. Commun. 2015, 51 (84), 15446-15449.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H300-H310-H330-H314-H318

Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P301+P310-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,3792
Beilstein
878140
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2905.59
TSCA
Yes
RTECS
KJ8225000

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf