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Ammonium peroxydisulfate is widely utilized as an oxidizing agent and radical initiators in the polymerization of certain alkenes. It is actively involved in in the synthesis of commercially important polymers like styrene-butadiene rubber and polytetrafluoroethylene. It combines with tetramethylethylenediamine to catalyze the polymerization of acrylamide. Due to its oxidizing properties, it can be employed to etch copper on printed circuit boards which is an alternative to ferric chloride solution. Also, it acts as oxidants in organic synthesis.
In combination with AgNO3 and Cu(OAc)2, promotes a carbamoyl radical process for the conversion of oxalic acid monoamides to isocyanates: J. Org. Chem., 60, 5430 (1995).
Hosseini, S. H. Kinetics study of copolymerization of 2-anilinoethanol onto chitosan by ammonium peroxydisulfate as a initiator. Int. J. Phys. Sci. 2015, 10 (4), 142-154.
Gopalakrishnan, k.; Sultan, S.; Govindaraj, A.; Rao, C. N. R. Supercapacitors based on composites of PANI with nanosheets of nitrogen-doped RGO, BC1.5N, MoS2and WS2. Nano Energy 2015, 12 52-58.
Gefahrenhinweise (EU): H272-H302-H315-H319-H334-H317-H335
May intensify fire; oxidizer. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation.
Take any precaution to avoid mixing with combustibles. Wear respiratory protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.