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Trimethyl phosphate is used as a color inhibitor for polyester and other polymer preparations, flame retardants and plasticizer. It acts as a solvent for aromatic halogenations and nitration reactions. It is used as a mild methylating reagent which is used in the dimethylation of aniline and related heterocyclic compound. Furthermore, it is involved in the synthesis of 1-methyl-pyridinium; dimethyl phosphate by reacting with pyridine.
Alternative to dimethyl sulfate for preparation of methyl esters of hindered carboxylic acids: Chem. Ind. (London), 1002 (1973). Used in N,N-dimethylation of aromatic amines, avoiding quaternization: Org. Synth. Coll., 5, 1085 (1973), and in N-methylation of nitrogen heterocycles, e.g. pyrimidines and imidazoles: J. Chem. Soc., Perkin 1, 391, 2506 (1973).
Matsumoto, K.; Martinez, M.; Gutel, T.; Mailley, S.; Patoux, S.; Inoue, K.; Utsugi, K. Stability of trimethyl phosphate non-flammable based electrolyte on the high voltage cathode (LiNi0.5Mn1.5O4). J. Power Sources 2015, 273, 1084-1088.
Luo, W. H.; Zhao, L. H. Inorganic-organic hybrid membranes with anhydrous proton conduction prepared from tetraethoxysilane, 3-glycidyloxypropyltrimethoxysilane, trimethyl phosphate and diethylethylammonium trifluoromethanesulfonate. J. Membr. Sci. 2014, 451, 32-39.
Gefahrenhinweise (EU): H302-H315-H319-H340-H351
Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause genetic defects. Suspected of causing cancer.
Obtain special instructions before use. IF exposed or if you feel unwell: