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96-32-2 - Methyl bromoacetate, 98+% - Bromoacetic acid methyl ester - A10605 - Alfa Aesar

A10605 Methyl bromoacetate, 98+%

CAS-Nummer
96-32-2
Synonyme
Bromoacetic acid methyl ester

Größe Preis ($) Menge Verfügbarkeit
50g 35,43
250g 95,69
1000g 284,28
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Methyl bromoacetate, 98+%

MDL
MFCD00000189
EINECS
202-499-2

Chemische Eigenschaften

Formel
C3H5BrO2
Molmasse
152.98
Schmelzpunkt
-50°
Siedepunkt
144-145°
Flammpunkt
62°(143°F)
Dichte
1.655
Brechungsindex
1.4585
Löslichkeit
Miscible with methanol, ether and acetone. Slightly miscible with water

Anwendungen

Methyl bromoacetate is used in the synthesis of coumarins and cis-cyclopropanes. It reacts with the conjugate base of (methylmethoxycarbene)pentacarbonylchromium(0) to prepare alkylated carbene complexes. Further, it is used to make vitamins and pharmaceuticals.

Bemerkungen

Incompatible with acids, bases, oxidizing agents and reducing agents.

Literaturverweise

Dib, J.; Schlörer, N.; Schänzer, W.; Thevis, M. Studies on the collision-induced dissociation of adipoR agonists after electrospray ionization and their implementation in sports drug testing. J. Mass Spectrom. 2015, 50 (2), 407-417.

Hoashi, Y.; Takai, T.; Koike, T.; Uchikawa, O. Synthesis of a novel tricyclic 1, 6, 7, 8-tetrahydro-2H-cyclopenta [b] furo [3, 2-d] pyridine derivative, the 5-aza analog of ramelteon. Tetrahedron Lett. 2014, 55 (29), 4014-4016.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H311-H331-H314-H318-H227

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Combustible liquid.

Sicherheitshinweise: P210-P260-P261-P301+P310-P303+P361+P353-P305+P351+P338-P361-P301+P330+P331-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
506256
Gefahrenklasse
6.1
Verpackungsgruppe
II
Harmonized Tariff Code
2915.90
TSCA
Yes
RTECS
AF6300000

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