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364-78-3 - 4-Fluoro-2-nitroaniline, 98% - A10685 - Alfa Aesar

A10685 4-Fluoro-2-nitroaniline, 98%

CAS-Nummer
364-78-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
50g 104,84
100g 185,60
500g 795,60
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4-Fluoro-2-nitroaniline, 98%

MDL
MFCD00007830
EINECS
206-666-0

Chemische Eigenschaften

Formel
C6H5FN2O2
Molmasse
156.12
Schmelzpunkt
90-94°
Flammpunkt
89°(192°F)
Löslichkeit
Insoluble in water.

Anwendungen

4-Fluoro-2-nitroaniline is used as a reagent in the preparation of 4-fluoro-o-phenylenediamine, 4-fluoro-N-ethyl-2-nitroaniline and N-(4-fluoro-2-nitrophenyl)-beta-alanine. It is also employed as a pharmaceutical intermediate. It acts as monodendate O-bonded ligand used in the coordination chemistry to form complexes with copper(II), nickel(II) and cobalt(II).

Bemerkungen

Incompatible with strong oxidizing agents, strong bases and strong acids.

Literaturverweise

Nale, D. B.; Bhanage, B. M. Copper-catalyzed efficient synthesis of a 2-benzimidazolone scaffold from 2-nitroaniline and dimethyl carbonate via a hydrosilylation reaction. Green Chem. 2015, 17 (4), 2480-2486.

Baumann, M.; Baxendale, I. R.; Hornung, C. H.; Ley, S. V.; Rojo, M. V.; Roper, K. A. Synthesis of Riboflavines, Quinoxalinones and Benzodiazepines through Chemoselective Flow Based Hydrogenations. Molecules 2014, 19 (7), 9736-9759.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H311-H332-H315-H319-H335

Toxic if swallowed. Toxic in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P301+P310-P305+P351+P338-P361-P304+P340-P362-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2210197
Harmonized Tariff Code
2921.42
TSCA
No

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