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2-Allylphenol is an protected intermediate in the synthesis of metabolites of Diclofenac (D436450), a nonsteroidal anti-inflammatory compound an decycloxygenase (COX) inhibitor.
Daniele Reyx; Irene Campistron; Christophe Caillaud; Martine Villatte; Annick Cavedon. Thermal reaction between N-phenylmaleimide and 2-allylphenol as a model for the crosslinking reaction in bismaleimide polymerization with diallylbisphenol A. Macromolecular Chemistry and Physics. 1995, 196, (3),775-785
Ted Schaefer; Rudy Sebastian; Timothy A.Wildman. The allyl and benzyl groups as hydrogen bond acceptors in derivatives of 2-allylphenol and 2-benzylphenol. Canadian Journal of Chemistry. 1979, 57, (22),3005-3009
Undergoes phosphine-free Pd-catalyzed cross-coupling with vinylic halides and triflates to give dihydrobenzopyrans: Tetrahedron Lett., 39, 237 (1998); for reaction scheme, see Palladium(II) acetate, 10516.
Gefahrenhinweise (EU): H227-H301-H311-H314-H318
Combustible liquid. Toxic if swallowed. Toxic in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage.
Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.