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127-06-0 - Acetone oxime, 98% - Acetoxime - 2-Propanone oxime - A10802 - Alfa Aesar

A10802 Acetone oxime, 98%

CAS-Nummer
127-06-0
Synonyme
Acetoxime
2-Propanone oxime

Größe Preis ($) Menge Verfügbarkeit
50g 18,32
250g 60,93
1000g 207,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Acetone oxime, 98%

MDL
MFCD00002118
EINECS
204-820-1

Chemische Eigenschaften

Formel
C3H7NO
Molmasse
73.10
Schmelzpunkt
60-63°
Siedepunkt
133-135°
Flammpunkt
60°(140°F)
Dichte
0.901
Löslichkeit
Soluble in water (330 g/L at 20°C).

Anwendungen

It is an intermediate used in organic synthesis and in agriculture. It is also an important raw material.

Bemerkungen

Store away from oxidizing agents. Protect against electrostatic charges.

Literaturverweise

Jianjun Wu.; Sarah C. Larsen. Solid-State Nuclear Magnetic Resonance Study of Acetone Oxime Adsorbed on CuZSM-5 and on HZSM-5. Journal of Catalysis. 1999, 182, (1), 244-256.

Karl Sohlberg.; Scott P. Leary.; Noel L. Owen.; Boris A. Trofimov. The infrared spectrum and conformation of acetone oxime vinyl ether. Vibrational Spectroscopy. 1997, 13, (2), 227-234.

Aldehydes and ketones can be converted to their oximes in high yield by an exchange process involving heating with acetone oxime in acetic acid at 110o: J. Prakt. Chem., 331, 870 (1989).

N-Protected form of hydroxylamine. For O-alkylation with sodium bromoacetate, and acid hydrolysis to O-carboxymethylhydroxylamine hydrochloride, see: Org. Synth. Coll., 3, 172 (1955).

For use of this and other simple oximes in the formation, by DCC-coupling, of active esters of N-protected oligopeptides, which react with C-protected amino acids to give peptides in high yield, see: Chem. Pharm. Bull., 17, 2937 (1969). See Appendix 6.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H228

Flammable solid.

Sicherheitshinweise: P210-P280-P240-P241-P370+P378a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.

Weitere Referenzen

Merck
14,75
Beilstein
1560146
Gefahrenklasse
4.1
Verpackungsgruppe
III
Harmonized Tariff Code
2928.00
TSCA
Yes
RTECS
AL6825000

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