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536-90-3 - m-Anisidine, 98% - 3-Aminoanisole - 3-Methoxyaniline - A10815 - Alfa Aesar

A10815 m-Anisidine, 98%

CAS-Nummer
536-90-3
Synonyme
3-Aminoanisole
3-Methoxyaniline

Größe Preis ($) Menge Verfügbarkeit
50g 30,68
250g 102,60
1000g 259,20
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

m-Anisidine, 98%

MDL
MFCD00007783
EINECS
208-651-4

Chemische Eigenschaften

Formel
C7H9NO
Molmasse
123.16
Schmelzpunkt
-1°
Siedepunkt
250-251°
Flammpunkt
126°(258°F)
Dichte
1.101
Brechungsindex
1.5810
Sensitivität
Light Sensitive
Löslichkeit
Soluble in water(18g/L).

Anwendungen

The unusually large amount of dibromo product produced upon bromination of m-anisidine may be attributed to the two doubly activeated positions. The best enantioselectivity of 97 % ee was observed for the reaction of m-anisidine in organocatalytic asymmetric three-component cyclization of cinnamaldehydes and primary amines with 1, 3-Dicarbonyl Compounds. Evidence for the control of 2nd-harmonic generation activities from the x-ray crystal-structures of the complexes of l-tartaric acid with m-anisidine and p-toluidine was determined.

Bemerkungen

Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literaturverweise

W. Preston Reeves,; Rufus M. King . A Convenient Method for Bromination of Aromatic Amines. Synthetic Communications: An International Journal for Rapid Communication of Synthetic Organic Chemistry . 1993, 23 (6), 855-859.

Renuka K,; RowTNG,; Prasad BR,; Subramanian CK,;Bhattacharya, S .Hydrogen-Bond-Directed Nonlinear-Optical Organic Materials - Evidence For The Control Of 2nd-Harmonic Generation Activities From The X-Ray Crystal-Structures Of The Complexes Of L-Tartaric Acid With M-Anisidine and P-Toluidine . Hydrogen-Bond-Directed Nonlinear-Optical Organic Materials. 1995, 19 (1), 83-89..

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H400-H410-H302-H315-H319-H335

Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P273-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,667
Beilstein
386119
Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2922.29
TSCA
Yes
RTECS
BZ5408000

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