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6136-68-1 - 3-Acetylbenzonitrile, 97+% - 3'-Cyanoacetophenone - A10841 - Alfa Aesar

A10841 3-Acetylbenzonitrile, 97+%

CAS-Nummer
6136-68-1
Synonyme
3'-Cyanoacetophenone

Größe Preis ($) Menge Verfügbarkeit
5g 66,06
25g 215,20
100g 731,20
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3-Acetylbenzonitrile, 97+%

MDL
MFCD00001806
EINECS
228-110-6

Chemische Eigenschaften

Formel
C9H7NO
Molmasse
145.16
Schmelzpunkt
97-101°
Siedepunkt
120°/5mm
Löslichkeit
Insoluble in water.

Anwendungen

Preparation of (q2-2-Acetyl-4-cyanophenyl)tetra- carbonylmanganese by Reaction of 3-Acetylbenzonitrile with Benzylpentacarbonylmanganese. Four aromatic amidoximes were synthesized by reacting hydroxylamine with 1,3 -dicyanobenzene, 1,4- dicyanobenzene, 3-acetylbenzonitrile, and 4-acetylbenzonitrile. Darzens condensation of 3-acetylbenzonitrile provided aldehyde.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Literaturverweise

Luísa M.P.F. Amaral,; Piotr Szterner,; Victor M.F. Morais,; Manuel A.V. Ribeiro da Silva. Thermochemical study of the isomeric compounds: 3-acetylbenzonitrile and benzoylacetonitrile. The Journal of Chemical Thermodynamics 2015, 91452-458.

Corrine Y. Watsona,; William J.D. Whishb,; Michael D. Threadgilla. Synthesis of 3-Substituted Benzamides and 5-Substituted Isoquinolin-1(2H)-ones and Preliminary Evaluation as Inhibitors of Poly(ADP-ribose)polymerase (PARP) . Bioorganic & Medicinal Chemistry. 1998, 6 (6), 721-734.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H331-H302-H312-H315-H319-H335

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P311-P362-P301+P312-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2079629
Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2926.90
TSCA
No

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