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699-12-7 - 2-(Phenylthio)ethanol, 99% - 2-Hydroxyethyl phenyl sulfide - A10861 - Alfa Aesar

A10861 2-(Phenylthio)ethanol, 99%

CAS-Nummer
699-12-7
Synonyme
2-Hydroxyethyl phenyl sulfide

Größe Preis ($) Menge Verfügbarkeit
10g 22,45
50g 59,94
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2-(Phenylthio)ethanol, 99%

MDL
MFCD00002905
EINECS
211-828-9

Chemische Eigenschaften

Formel
C6H5S(CH2)2OH
Molmasse
154.23
Siedepunkt
115-116°/2mm
Flammpunkt
>110°(230°F)
Dichte
1.147
Brechungsindex
1.5920

Literaturverweise

Reagent for phosphate protection in oligonucleotide synthesis. The resulting esters are stable to base, sulfonylation, and to mild acid, but can be deprotected by periodate oxidation to the sulfoxide: Can. J. Chem., 50, 456, 769 (1972), or NCS oxidation to the sulfone: J. Am. Chem. Soc., 95, 2020 (1973), either of which can then be cleaved by base-induced elimination. For use in pyrimidine protection of thymidine analogs, via Mitsunobu N-alkylation, m-CPBA oxidation to the sulfone and cleavage with dilute NaOH, see: Synlett, 845 (2006).

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Weitere Referenzen

Beilstein
1860057
Harmonized Tariff Code
2930.90
TSCA
Yes

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