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ET catalysis of Au25 in intramolecular cascade reaction of 2-nitrobenzonitrile, from which 2-amniobenzamide (a precursor of significant pharmaceuticals20,21) is produced with high yield. fluorodenitration of 2-nitrobenzonitrile with Rb18F in DMSO gave an 85% yield of the 18F-labelled benzonitrile after only 20 minutes at 150°C.
Hanbao Chong,; Peng Li,; Shuxin Wang,; Fangyu Fu,; Ji Xiang,; Manzhou Zhu,; Yadong Li. Au25 Clusters as Electron-Transfer Catalysts Induced the Intramolecular Cascade Reaction of 2-nitrobenzonitrile. Scientific Reports. 2013 , 3
Klara Koprivova,; Libor Cerveny. Hydrogenation of nitrobenzonitriles using Raney nickel catalyst. : Research on Chemical Intermediates. 2008, 34 (1), 93.
Gefahrenhinweise (EU): H300-H311
Fatal if swallowed. Toxic in contact with skin.
Wear protective gloves/clothing. IF exposed or if you feel unwell: Immediately call a POISON CENTER/doctor IF ON SKIN: Wash with plenty of water.