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1068-57-1 - Acetic hydrazide, 96% - Acethydrazide - Acetylhydrazine - A10969 - Alfa Aesar

A10969 Acetic hydrazide, 96%

CAS-Nummer
1068-57-1
Synonyme
Acethydrazide
Acetylhydrazine

Größe Preis ($) Menge Verfügbarkeit
25g 49,44
100g 136,35
500g 405,26
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Acetic hydrazide, 96%

MDL
MFCD00007610
EINECS
213-948-7

Chemische Eigenschaften

Formel
CH3CONHNH2
Molmasse
74.08
Schmelzpunkt
ca 60-68°
Siedepunkt
128-129°/18mm
Flammpunkt
>110°(230°F)
Sensitivität
Hygroscopic
Löslichkeit
Soluble in water.

Anwendungen

Acetic hydrazide is used as an antibiotic for the treatment of mycobacterium tuberculosis. It is also involved in the preparation of sunitinib b reacting with 5-fluoroisatin. Further, it inhibits mycolic acid biosynthesis. It serves as an important intermediate in organic synthesis such as nitric furosemide Long (nifuratrone) in medicine.

Bemerkungen

Hygroscopic. Incompatible with strong bases.

Literaturverweise

Sadhukhan, D.; Maiti, M.; Pilet, G.; Bauzá, A.; Frontera, A.; Mitra, S. Hydrogen Bond, pi-pi, and CH-pi Interactions Governing the Supramolecular Assembly of Some Hydrazone Ligands and Their MnII Complexes - Structural and Theoretical Interpretation. Eur. J. Inorg. Chem. 2015, 2015 (11), 1958-1972.

Sadhukhan, D.; Maiti, M.; Zangrando, E.; Pathan, S.; Mitra, S.; Patel, A. Heterogeneous catalytic oxidation of styrene by an oxo bridged divanadium(V) complex of an acetohydrazide-Schiff base. Polyhedron 2014, 69, 1-9.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
506165
Harmonized Tariff Code
2928.00
TSCA
Yes
RTECS
AI1225000

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