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593-71-5 - Chloroiodomethane, 98%, stab. with copper - Methylene chloroiodide - A11032 - Alfa Aesar

A11032 Chloroiodomethane, 98%, stab. with copper

CAS-Nummer
593-71-5
Synonyme
Methylene chloroiodide

Größe Preis ($) Menge Verfügbarkeit
10g 36,67
50g 118,45
250g 449,08
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Chloroiodomethane, 98%, stab. with copper

MDL
MFCD00001078
EINECS
209-804-8

Chemische Eigenschaften

Formel
ClCH2I
Molmasse
176.38
Siedepunkt
108-109°
Flammpunkt
None
Dichte
2.416
Brechungsindex
1.5822
Sensitivität
Light Sensitive
Löslichkeit
Miscible with acetone, benzene, diethyl ether and alcohol.

Anwendungen

Chloroiodomethane is used as an intermediate in pharmaceuticals, organic synthesis, agrochemicals and dyestuff. It is also useful in cyclopropanation (Simmon-Smith reaction), Mannich reaction, aminomethylation and in epoxidation.

Bemerkungen

It is incompatible with strong oxidizing agents and strong bases.

Literaturverweise

Degennaro, L.; Fanelli, F.; Giovine, A.; Luisi, R. External Trapping of Halomethyllithium Enabled by Flow Microreactors. Adv. Synth. Catal. 2015, 357 (1), 21-27.

Ooki, A.; Nomura, D.; Nishino, S.; Kikuchi, T.; Yokouchi, Y. A global-scale map of isoprene and volatile organic iodine in surface seawater of the Arctic, Northwest Pacific, Indian, and Southern Oceans. J. Geophys. Res. Oceans 2015, 120 (6), 4108-4128.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1730802
Gefahrenklasse
6.1
Harmonized Tariff Code
2903.79
TSCA
No

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