Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

3433-80-5 - 2-Bromobenzyl bromide, 98% - alpha,2-Dibromotoluene - A11285 - Alfa Aesar

A11285 2-Bromobenzyl bromide, 98%

CAS-Nummer
3433-80-5
Synonyme
alpha,2-Dibromotoluene

Größe Preis ($) Menge Verfügbarkeit
10g 39,88
50g 118,45
250g 423,09
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

2-Bromobenzyl bromide, 98%

MDL
MFCD00000173
EINECS
222-334-8

Chemische Eigenschaften

Formel
C7H6Br2
Molmasse
249.94
Schmelzpunkt
29-32°
Siedepunkt
127-129°/19mm
Flammpunkt
>110°(230°F)
Brechungsindex
1.6190
Löslichkeit
Insoluble in water.

Anwendungen

2-Bromobenzyl bromide was used in the synthesis of substituted quinazolines and 1,2,3,4-tetrahydroquinazolines, 2- and 3-substituted indenes, tris-2-bromotribenzylamine3.

Bemerkungen

Store away from strong bases and oxidizing agents. Incompatible with amines, alcohols, steel.

Literaturverweise

Ronald L. Halterman; Chengian Zhu. Efficient synthesis of 2- and 3-substituted indenes from 2-bromobenzyl bromide through an enolate alkylation/Cr(II)/Ni(II)-mediated carbonyl addition sequence. Tetrahedron letters 1999, 40, 7445-7448.

Yao Dai; Xiujuan Feng; Hesong Liu; Hua Jiang and Ming Bao. Synthesis of 2-Naphthols via Carbonylative Stille Coupling Reaction of 2-Bromobenzyl Bromides with Tributylallylstannane Followed by the Heck Reaction. J. Org. Chem.2011, 76, (24)10068-10077.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
971015
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2903.99
TSCA
Yes

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf