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Tropolone is a sensitive reagent for reducing sugars. A non-benzenoid aromatic compound, Reagent for the preparation of fused heterocycles and complexes of Ga(III) and In(III).
R.L. Redington, T.E. Redington. Tropolone monomer: Vibrational spectrum and proton tunneling. Journal of Molecular Spectroscopy. 1979, 78, (2), 229-247.
Yasushi Tomioka.; Mitsuo Ito.; Naohiko Mikami. Electronic spectra of tropolone in a supersonic free jet. Proton tunneling in the S1 state. J. Phys. Chem. 1983, 87, (22), 4401-4405.
Reagent for Rh: Mikrochim. Acta, 459 (1972).
Non-benzenoid aromatic system, analogous to phenol. For a review of 7-membered conjugated cyclic systems, see: Chem. Rev., 73, 293 (1973). For a study of the role of chelation and resonance in the intrinsic acidity and basicity of tropolone, see: J. Org. Chem., 62, 3200 (1997).
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