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2396-63-6 - 1,6-Heptadiyne, 97% - A11318 - Alfa Aesar

A11318 1,6-Heptadiyne, 97%

CAS-Nummer
2396-63-6
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 98,00
25g 415,00
100g 1320,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

1,6-Heptadiyne, 97%

MDL
MFCD00014925
EINECS
219-253-5

Chemische Eigenschaften

Formel
C7H8
Molmasse
92.14
Siedepunkt
109-111°
Flammpunkt
9°(48°F)
Dichte
0.810
Brechungsindex
1.4420
Löslichkeit
Insoluble in water.

Anwendungen

1,6-Heptadiyne may be used in the preparation of free-standing polymer films of poly(1,6-heptadiyne). Polymerization of 1,6-heptadiyne using an insoluble Zeigler-Natta catalyst affords soluble polymer having six-membered ring containing polyene. Ruthenium(II)-catalyzed reaction of a substituted 1,6-heptadiyne with norbornene affords a tandem [2+ 2+ 2]/[4+2] cycloaddition product and a [2+ 2+2] cycloadduct.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents. Haevy metal powder, heat. Refrigerate at (+4°C).

Literaturverweise

Gibson HW, et al. . Poly (1, 6-heptadiyne), a free-standing polymer film dopable to high electrical conductivity. . J. Am. Chem. Soc. 1983, 105(13), 4417-31.

Yamamoto Y, et al. Ruthenium-catalyzed tandem [2+ 2+ 2]/[4+ 2] cycloaddition of 1, 6-heptadiyne with norbornene. . Journal name. 1998, 17 (10), 1910-12.

Undergoes [2+2+2] cyclotrimerization, e.g. with propargyl alcohol, catalyzed by Chlorotris(triphenyl­phosphine)­rhodium(I)­, 10468: J. Chem. Soc., Perkin 1, 1357 (1988):

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H303-H304

Highly flammable liquid and vapour. May be harmful if swallowed. May be fatal if swallowed and enters airways.

Sicherheitshinweise: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1731756
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2901.29
TSCA
Yes
RTECS
MI5600000

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