Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

7252-83-7 - Bromoacetaldehyde dimethyl acetal, 97+%, stab. with potassium carbonate - 2-Bromo-1,1-dimethoxyethane - A11324 - Alfa Aesar

A11324 Bromoacetaldehyde dimethyl acetal, 97+%, stab. with potassium carbonate

CAS-Nummer
7252-83-7
Synonyme
2-Bromo-1,1-dimethoxyethane

Größe Preis ($) Menge Verfügbarkeit
25g 21,73
250g 135,96
1000g 376,80
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Bromoacetaldehyde dimethyl acetal, 97+%, stab. with potassium carbonate

MDL
MFCD00000213
EINECS
230-669-6

Chemische Eigenschaften

Formel
C6H13BrO2
Molmasse
169.03
Siedepunkt
150°
Flammpunkt
54°(129°F)
Dichte
1.435
Brechungsindex
1.4450
Sensitivität
Moisture Sensitive
Löslichkeit
Insoluble in water.

Anwendungen

2-Bromo-1,1-dimethoxyethane (Bromoacetaldehyde dimethyl acetal) was used in the synthesis of 2,3-O-acetal via reaction with 2,3-diol in the presence of 10-camphorsulphonic acid (CSA). 2-bromo-1,1-dimethoxyethane was used to react with 4-hydroxylbenzaldehyde, and finally aldehyde substituted prodrug was generated by TFA-mediated deacetalization.

Bemerkungen

Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, moisture.

Literaturverweise

Zunyi Yanga,; Hongzhi Caoa,; Jie Hua,; Renli Shanb;, Biao Yua. 1?2 Migration and concurrent glycosidation of phenyl 1-thio-α-mannopyranosides via 2, 3-O-cyclic dioxonium intermediates.. Tetrahedron. 2003, 59 (2), 249-254.

Chunyan Bao,; Ming Jin,; Bo Li,; Yaodong Xu,; Jingyan Jin,; Linyong Zhu. Long conjugated 2-nitrobenzyl derivative caged anticancer prodrugs with visible light regulated release: preparation and functionalizations. title . Org. Biomol. Chem.. 2012, 10 (27), 5238-5244.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H330-H315-H319-H335-H226

Toxic if swallowed. Fatal if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Flammable liquid and vapour.

Sicherheitshinweise: P280h-P305+P351+P338-P309-P310

Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Weitere Referenzen

Beilstein
1280132
Gefahrenklasse
6.1
Verpackungsgruppe
II
Harmonized Tariff Code
2911.00
TSCA
Yes

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf