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108-86-1 - Bromobenzene, 99% - A11407 - Alfa Aesar

A11407 Bromobenzene, 99%

CAS-Nummer
108-86-1
Synonyme

Größe Preis ($) Menge Verfügbarkeit
500g 30,08
2500g 97,85
10000g 306,94
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

Bromobenzene, 99%

MDL
MFCD00000055
EINECS
203-623-8

Chemische Eigenschaften

Formel
C6H5Br
Molmasse
157.02
Schmelzpunkt
-31°
Siedepunkt
155-156°
Flammpunkt
51°(123°F)
Dichte
1.492
Brechungsindex
1.5590
Löslichkeit
Miscible with diethyl ether, alcohol, carbon tetrachloride, chloroform and benzene.

Anwendungen

Bromobenzene is used as solvent in organic synthesis. It is used to prepare the phenylmagnesium bromide, a Grignard reagent, an intermediate in the preparation of benzoic acid by reacting with carbon dioxide. It is a precursor for making phencyclidine. It is useful for the introduction of phenyl group through palladium-catalyzed coupling reactions viz. the Suzuki reaction.

Bemerkungen

Store in cool place. Avoid inhalation of vapor or mist. Incompatible with strong oxidizing agents.

Literaturverweise

Man, I. C.; Şoriga, Ş. G.; Pârvulescu, V. Theoretical study of the adsorption of bromobenzene and aniline on Cu2O(1 1 0):CuO and Cu2O(1 1 1):CuO surfaces. Chem. Phys. Lett. 2014, 604, 38-45.

Zhang, X.; Borjian, S.; Baird, M. C. An unusual product distribution from the reaction of Pd(η3-1-PhC3H4)(η5-C5H5) with a deficiency of PPh3 in the presence of bromobenzene. Transition Met. Chem. 2015, 40 (2), 125-129.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H226-H315-H303-H411

Flammable liquid and vapour. Causes skin irritation. May be harmful if swallowed. Toxic to aquatic life with long lasting effects.

Sicherheitshinweise: P210-P273-P280-P240-P241-P303+P361+P353-P362-P312-P403+P235-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,1406
Beilstein
1236661
Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
CY9000000

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