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1734-79-8 - 4-Nitrocinnamaldehyde, predominantly trans, 98% - A11467 - Alfa Aesar

A11467 4-Nitrocinnamaldehyde, predominantly trans, 98%

CAS-Nummer
1734-79-8
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 87,55
25g 312,30
50g 497,60
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4-Nitrocinnamaldehyde, predominantly trans, 98%

MDL
MFCD00007379
EINECS
217-076-8

Chemische Eigenschaften

Formel
C9H7NO3
Molmasse
177.16
Schmelzpunkt
138-142°
Sensitivität
Air Sensitive
Löslichkeit
Insoluble in water.

Anwendungen

Doebner-Miller reaction the 4- nitrocinnamaldehyde and 2-methylaniline in concentrated HC1 give the corresponding 8-methyl-2-phenylquinoline (3: R = 4'-N02) directly. The asymmetric Friedel-Crafts-type alkylation in aqueous media reaction of 4-Nitrocinnamaldehydr with N-methyl indole using trifluoroacetic acid (TFA) salt of the PEG-PS-supported prolyl peptide having the polyleucine tether as a catalyst. 4-Nitrocinnamaldehyde has been used in the preparation of 2, 2?-[(E)-3-(4-nitrophenyl) prop-2-ene-1,1-diyl] bis(3-hydroxy-5, 5-dimethylcyclohex-2-en-1-one).

Bemerkungen

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air.

Literaturverweise

Graham J. Atwell,; Bruce C. Baguley,; William A. Denny. Potential antitumor agents. 57. 2-Phenylquinoline-8-carboxamides as minimal DNA-intercalating antitumor agents with in vivo solid tumor activity . J. Med. Chem. 1989, 32(2),396-401.

Kengo Akagawa,; Takuhiro Yamashita,; Seiji Sakamoto,; Kazuaki Kudo. Friedel-Crafts-type alkylation in aqueous media using resin-supported peptide catalyst having polyleucine. Tetrahedron Letters. 2009, 50 (40) ,5602-5604.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Beilstein
1565424
Harmonized Tariff Code
2913.00
TSCA
Yes
RTECS
GD6650000

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