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383-67-5 - Allyl trifluoroacetate, 97% - Trifluoroacetic acid allyl ester - A11690 - Alfa Aesar

A11690 Allyl trifluoroacetate, 97%

CAS-Nummer
383-67-5
Synonyme
Trifluoroacetic acid allyl ester

Größe Preis ($) Menge Verfügbarkeit
10g 31,93
50g 102,60
250g 442,00
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Allyl trifluoroacetate, 97%

MDL
MFCD00013567
EINECS
206-853-7

Chemische Eigenschaften

Formel
CH2=CHCH2O2CCF3
Molmasse
154.09
Siedepunkt
73-75°
Flammpunkt
-1°(30°F)
Dichte
1.183
Brechungsindex
1.3360
Löslichkeit
Not miscible or difficult to mix with water.

Anwendungen

Used as nucleophilic ally metal precursor in alkylation reaction that generates homoallylic amines. Also used as chemical reagent and intermediate for pharmaceutical.

Bemerkungen

Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

Literaturverweise

Robin E. Grote; and Elizabeth R. Jarvo. Palladium-Catalyzed, One-Pot, Three-Component Synthesis of Homoallylic Amines from Aldehydes, Anisidine, and Allyl Trifluoroacetate. Org. Lett. 2009, 11 (2), 485-488.

Debby de Groot; Janine C. de Wilde; Richard J. van Haaren; Joost N. H. Reek; Paul C. J. Kamer; Piet W. N. M. van Leeuwen; Eva B. Eggeling; Dieter Vogt; Huub Kooijman; Anthony L. Spek and Alexander W. van der Made . Palladium complexes of phosphine functionalised carbosilane dendrimers as catalysts in a continuous flow membrane reactor. Chem. Commun. 1999, (17), 1623-1624.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P210-P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1766312
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2915.90
TSCA
No

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