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2637-34-5 - 2-Mercaptopyridine, 98% - 2-Pyridinethiol - A11741 - Alfa Aesar

A11741 2-Mercaptopyridine, 98%

CAS-Nummer
2637-34-5
Synonyme
2-Pyridinethiol

Größe Preis ($) Menge Verfügbarkeit
5g 18,72
25g 64,80
100g 174,40
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2-Mercaptopyridine, 98%

MDL
MFCD00006285
EINECS
220-131-9

Chemische Eigenschaften

Formel
C5H5NS
Molmasse
111.17
Schmelzpunkt
124-130°
Sensitivität
Air Sensitive
Löslichkeit
Slightly soluble in chloroform, methanol and dimethyl sulfoxide.

Anwendungen

Employed as a ligand in metal complexes. It can be used to coat porous media to purify plasmid DNA.

Bemerkungen

Air Sensitive, keep the container tightly sealed. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Literaturverweise

David B Cordes; and Lyall R Hanton. Structural invariance in silver(I) coordination networks formed using flexible four-armed thiopyridine ligands. Inorganic Chemistry. 2007, 46 (5), 1634-1644.

Alexey V Chuchuryukin et. al. Hydroxy- and mercaptopyridine pincer platinum and palladium complexes generated by silver-free halide abstraction. Inorganic Chemistry, 2006, 45 (5), 2045-2054.

S-Acyl derivatives react with Grignard reagents in a high-yielding synthesis of ketones: J. Am. Chem. Soc., 95, 4763 (1973):

Titanium enolates of S-acyl derivatives react with imines in a one pot synthesis of ß-lactams: J. Org. Chem., 57, 4155 (1992).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
105758
Harmonized Tariff Code
2933.39
TSCA
Yes
RTECS
UT9600000

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