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5780-36-9 - 2-(Methylthio)thiophene, 97% - 2-(Methylmercapto)thiophene - Methyl 2-thienyl sulfide - A11763 - Alfa Aesar

A11763 2-(Methylthio)thiophene, 97%

CAS-Nummer
5780-36-9
Synonyme
2-(Methylmercapto)thiophene
Methyl 2-thienyl sulfide

Größe Preis ($) Menge Verfügbarkeit
1g 59,12
5g 152,00
25g 605,60
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2-(Methylthio)thiophene, 97%

MDL
MFCD00052382

Chemische Eigenschaften

Formel
C5H6S2
Molmasse
130.23
Siedepunkt
82-84°/15mm
Brechungsindex
1.5960

Anwendungen

2-(Methylthio)thiophene is used as an intermediate in synthetic chemistry. It is also used in the preparation of 2-thiocyanato-thiophene by reaction with cyanogen iodide using sodium methylmercatide as a reagent.

Bemerkungen

Incompatible with oxidizing agents.

Literaturverweise

Zhu, D.; Chang, D.; Shi, L. Transition-metal-free cross-coupling of thioethers with aryl(cyano)iodonium triflates: a facile and efficient method for the one-pot synthesis of thiocyanates. Chem. Comm. 2015, 51 (33), 7180-7183.

Yang, C.; Song, H. L.; Chen, F. Response Surface Methodology for Meat-like Odorants from Maillard Reaction with Glutathione I: the Optimization Analysis and the General Pathway Exploration. J. Food Sci. 2012, 77 (9), C966-C974.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H319-H335

Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P264-P305+P351+P338-P304+P340-P312-P337+P313-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. If eye irritation persists: Get medical advice/attention. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
106272
Gefahrenklasse
9
Verpackungsgruppe
III
Harmonized Tariff Code
2934.99
TSCA
No

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