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Allyl bromide is used as an alkylating agent in the synthesis of pharmaceuticals, polymers, adhesives, perfumes, biochemicals and other allylic compounds. It is used as precursor for the preparation of allyliczinc bromide by reacting it with zinc. It is also used in the preparation of allylethers like allyl decyl ether, allyl benzyl ether and allyl geranyl ether. It is also used in the preparation of R enantiomer of allyl phenyl carbinol (APC) such as 1-phenyl-3-butene, which is a valuable intermediate for drugs and agro-chemicals.
Pandey, G.; Kant, R.; Batra, S. A general route to the synthesis of indoloazocines using allyl bromides prepared from Morita-Baylis-Hillman adducts. Tetrahedron Lett. 2015, 56 (7), 930-933.
Fananas-Mastral, M.; Vitale, R.; Perez, M.; Feringa, B. L. Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Allylic Alkylation of (Z)-Allyl Bromides with Organolithium Reagents. Chem. Eur. J. 2015, 21 (11), 4209-4212.
Gefahrenhinweise (EU): H225-H301-H331-H314-H318-H340-H350
Highly flammable liquid and vapour. Toxic if swallowed. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. May cause genetic defects. May cause cancer.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.