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51-35-4 - trans-4-Hydroxy-L-proline, 99+% - (2S,4R)-(-)-4-Hydroxypyrrolidine-2-carboxylic acid - H-Hyp-OH - A11851 - Alfa Aesar

A11851 trans-4-Hydroxy-L-proline, 99+%

CAS-Nummer
51-35-4
Synonyme
(2S,4R)-(-)-4-Hydroxypyrrolidine-2-carboxylic acid
H-Hyp-OH

Größe Preis ($) Menge Verfügbarkeit
10g 34,20
25g 64,80
100g 189,00
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trans-4-Hydroxy-L-proline, 99+%

MDL
MFCD00064320
EINECS
200-091-9

Chemische Eigenschaften

Formel
C5H9NO3
Molmasse
131.13
Schmelzpunkt
270-273° dec.
Löslichkeit
Soluble in water.

Anwendungen

trans-4-Hydroxy-L-proline is used as a reagent for the preparation of neuroexcitatory kainoids and antifungal echinocandins. It is also involved in the synthesis of chiral ligands for enantioselective ethylation of aldehydes.

Bemerkungen

Incompatible with strong oxidizing agents.

Literaturverweise

Chiral precursor for a wide variety of synthetic targets. For discussion of some examples, see: Tetrahedron, 52, 13803 (1996).

Satomura, T.; Ishikura, M.; Koyanagi, T.; Sakuraba, H.; Ohshima, T.; Suye, S. I. Dye-linked d-amino acid dehydrogenase from the thermophilic bacterium Rhodothermus marinus JCM9785: characteristics and role in trans-4-hydroxy-l-proline catabolism. Appl. Microbiol. Biotechnol. 2015, 99 (10), 4265-4275.

Kuttan, R.; Panikkar, B.; Binitha, P. P. Amino acids in sandal (Santalum album L) with special reference to cis-4-hydroxy-l-proline and sym. homospermidine. Springerplus 2015, 4 (1), 1-9.

GHS Gefahren- und Sicherheitshinweise

Sicherheitshinweise: P260-P201-P280-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,4840
Beilstein
471933
Harmonized Tariff Code
2933.99
TSCA
Yes
RTECS
TW3586500

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