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13361-30-3 - Isopropyl cyanoacetate, 97% - Cyanoacetic acid isopropyl ester - A11887 - Alfa Aesar

A11887 Isopropyl cyanoacetate, 97%

CAS-Nummer
13361-30-3
Synonyme
Cyanoacetic acid isopropyl ester

Größe Preis ($) Menge Verfügbarkeit
25g 11,98
100g 32,43
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Isopropyl cyanoacetate, 97%

MDL
MFCD00019842
EINECS
236-421-3

Chemische Eigenschaften

Formel
NCCH2CO2CH(CH3)2
Molmasse
127.14
Siedepunkt
207°
Flammpunkt
92°(198°F)
Dichte
1.013
Brechungsindex
1.4150
Löslichkeit
Slightly soluble in water.

Anwendungen

Isopropyl cyanoacetate was used in the synthesis of 3-substituted coumarins by undergoing Knöevenagel reactions with aldehydes and ketones.

Bemerkungen

Store in cool, dry conditions in well sealed container. Store away from oxidizing agent.

Literaturverweise

Kohei Yamashita; Takanori Tanaka; Masahiko Hayashi. Use of isopropyl alcohol as a solvent in Ti(O-i-Pr)4-catalyzed Knöevenagel reactions. Tetrahedron,2005, 61(33), 7981-7985.

Chan Hyuk Kim; Ki Po Jang; Soo Young Choi; Young Keun Chung; and Eun Lee . A Carbonyl Ylide Cycloaddition Approach to Platensimycin. Angewandte Chemie International Edition,2008, 47(47), 4009-4011.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335-H227-H303

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid. May be harmful if swallowed.

Sicherheitshinweise: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1756014
Harmonized Tariff Code
2926.90
TSCA
No
RTECS
AG4270000

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