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32864-38-3 - tert-Butyl ethyl malonate, 95% - Malonic acid tert-butyl ethyl ester - A11927 - Alfa Aesar

A11927 tert-Butyl ethyl malonate, 95%

CAS-Nummer
32864-38-3
Synonyme
Malonic acid tert-butyl ethyl ester

Größe Preis ($) Menge Verfügbarkeit
5g 44,70
25g 157,00
100g 526,00
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tert-Butyl ethyl malonate, 95%

MDL
MFCD00009193
EINECS
251-269-8

Chemische Eigenschaften

Formel
C9H16O4
Molmasse
188.22
Siedepunkt
98-100°/22mm
Flammpunkt
87°(188°F)
Dichte
0.994
Brechungsindex
1.4160
Löslichkeit
Miscible with most common solvents. Immiscible with water.

Anwendungen

tert-Butyl ethyl malonate is used in the preparation of polar ester-functionalized aliphatic polysulfone. It is also a useful reagent for organic synthesis.

Bemerkungen

Incompatible with strong oxidizing agents.

Literaturverweise

Pellissier, H. Recent Developments in Enantioselective Nickel(II)-Catalyzed Conjugate Additions. Adv. Synth. Catal. 2015, 357 (13), 2745-2780.

Thomas, J. B.; Giddings, A. M.; Olepu, S.; Wiethe, R. W.; Warner, K. R.; Sarret, P.; Longpre, J. M.; Runyon, S. P.; Gilmour, B. P. The amide linker in nonpeptide neurotensin receptor ligands plays a key role in calcium signaling at the neurotensin receptor type 2. Bioorg. Med. Chem. Lett. 2015, 25 (10), 2060-2064.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H227

Combustible liquid.

Sicherheitshinweise: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1776681
Harmonized Tariff Code
2917.19
TSCA
No

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