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4-Methylmorpholine is used as a solvent for dyes, resins, waxes and pharmaceuticals. It acts as a crosslinker in the preparation of polyurethane foams, elastomers and adhesives. It is used as a precursor to prepare N-methylmorpholine N-oxide and morpholinium cation based ionic liquids. It is utilized as corrosion inhibitors and anti-scaling agents in industries.
Widely used base in peptide chemistry, milder than triethylamine. Recommended for the avoidance of racemization in the mixed anhydride method of coupling: J. Am. Chem. Soc., 88, 1338 (1966); 89, 5012 (1967). Also preferred in many cases for the formation of active esters or the neutralization of acid salts. For peptide reagents, see Appendix 6./n
Pancotti, A.; Parapini, S.; Agli, M. D.; Gambini, L.; Galli, C.; Sangiovanni, E.; Basilico, N.; Bosisio, E.; Taramelli, D.; Romeo, S. Discovery of oxybisbenzoylamides as a new class of antimalarial agents. Med. Chem. Commun. 2015, 6 (6), 1173-1177.
Leng, C.; Kish, J. D.; Roberts, J. E.; Dwebi, I.; Chon, N.; Liu, Y. Temperature-Dependent Henrys Law Constants of Atmospheric Amines. J. Phys. Chem. A 2015, 199 (33), 8884-8891.
Gefahrenhinweise (EU): H225-H302-H312-H332-H314-H318
Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.