Cookies disclaimer

I agree Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. You can disable the usage of cookies by changing the settings of your browser. By browsing our website without changing the browser settings you grant us permission to store that information on your device.

455-13-0 - 4-Iodobenzotrifluoride, 98% - 4-Iodo-alpha,alpha,alpha-trifluorotoluene - A12189 - Alfa Aesar

A12189 4-Iodobenzotrifluoride, 98%

CAS-Nummer
455-13-0
Synonyme
4-Iodo-alpha,alpha,alpha-trifluorotoluene

Größe Preis ($) Menge Verfügbarkeit
1g 23,04
5g 70,29
25g 246,60
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

4-Iodobenzotrifluoride, 98%

MDL
MFCD00039398
EINECS
207-234-4

Chemische Eigenschaften

Formel
C7H4F3I
Molmasse
272.01
Schmelzpunkt
-8°
Siedepunkt
68-70°/15mm
Flammpunkt
68°(154°F)
Dichte
1.851
Brechungsindex
1.5180
Sensitivität
Light Sensitive
Löslichkeit
Insoluble in water.

Anwendungen

4-Iodobenzotrifluoride may be employed as substrate with electron-deficient aromatic ring, during Mizoroki-Heck reaction with acrylic acid, to afford 4-trifluoromethylcinnnamic acid. It undergoes aminocarbonylation in DMF using phosphoryl chloride to give N,N-dimethyl-(4-trifluoromethyl)benzamide.

Bemerkungen

Light sensitive. Incompatible with strong oxidizing agents. Store in dark.

Literaturverweise

Atsushi Ohtaka; Tomohiro Yamaguchi; Takuto Teratani; Osamu Shimomura; Ryôki Nomura. Linear polystyrene-stabilized PdO nanoparticle-catalyzed Mizoroki-Heck reactions in water. Molecules. 2011, 16 (11), 9067-9076.

Kazushi Hosoi; Kyoko Nozaki; Tamejiro Hiyama. Carbon monoxide free aminocarbonylation of aryl and alkenyl iodides using DMF as an amide source. Organic Letters. 2002, 4 (17), 2849-2851.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335-H227

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. Combustible liquid.

Sicherheitshinweise: P210-P261-P280-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1944013
Harmonized Tariff Code
2903.99
TSCA
Yes

Empfohlen

Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

Katalysatoren

Forschungs- und Laborbedarf