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936-59-4 - 3-Chloropropiophenone, 96% - 2-Chloroethyl phenyl ketone - beta-Chloropropiophenone - A12290 - Alfa Aesar

A12290 3-Chloropropiophenone, 96%

CAS-Nummer
936-59-4
Synonyme
2-Chloroethyl phenyl ketone
beta-Chloropropiophenone

Größe Preis ($) Menge Verfügbarkeit
10g 44,91
50g 169,95
100g 232,80
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3-Chloropropiophenone, 96%

MDL
MFCD00000990
EINECS
213-317-6

Chemische Eigenschaften

Formel
C9H9ClO
Molmasse
168.62
Schmelzpunkt
46-50°
Siedepunkt
113-115°/4mm
Flammpunkt
>110°(230°F)
Löslichkeit
Insoluble in water.

Anwendungen

3-Chloropropiophenone was used in the asymmetric reduction of (S)-3-chloro-1-phenylpropanol using preheated Candida utilis cells immobilized in calcium alginate gel beads. It was also used in the synthesis of (R)-3-chloro-1-phenyl-1-propanol via asymmetric reduction using in-situ generated oxazaborolidine catalyst derived from (S)-α,α-diphenylprolinol. It is a precursor of phenyl vinyl ketone.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from strong oxidizing agents.

Literaturverweise

Yang Gen-Sheng; Xu Jiang-Yan; Ou Zhi-Min; Yao Shan-Jing. Asymmetric reduction of (S)-3-chloro-1-phenylpropanol from 3-chloropropiophenone by preheated immobilized Candida utilis. Biotechnology Letters. 2009, 31 (12), 1879-1883.

Yu-Chang Liu; Yan Liu; Zhong-Liu Wu. Synthesis of enantiopure glycidol derivatives via a one-pot two-step enzymatic cascade. Organic & Biomolecular Chemistry. 2015, 13 (7), 2146-2152.

Precursor of phenyl vinyl ketone.

Weitere Referenzen

Beilstein
2043580
Harmonized Tariff Code
2914.70
TSCA
Yes

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