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1821-36-9 - N-Cyclohexylaniline, 98% - N-Phenylcyclohexylamine - A12409 - Alfa Aesar

A12409 N-Cyclohexylaniline, 98%

CAS-Nummer
1821-36-9
Synonyme
N-Phenylcyclohexylamine

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N-Cyclohexylaniline, 98%

MDL
MFCD00014284
EINECS
217-344-4

Chemische Eigenschaften

Formel
C12H17N
Molmasse
175.28
Schmelzpunkt
14-15°
Siedepunkt
279°
Flammpunkt
136°(277°F)
Dichte
1.0155
Brechungsindex
1.560
Löslichkeit
Not miscible or difficult to mix in water.

Anwendungen

N-Cyclohexylaniline is used as reagent in palladium-catalyzed amination of aromatic bromides. It is also used to produce N-cyclohexyl-N-phenyl-urea at ambient temperature.

Bemerkungen

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Literaturverweise

Mahavir Prashad.; Xiao Yin Mak.; Yugang Liu.; Oljan Repic. Palladium-Catalyzed Amination of Aryl Bromides with Hindered N-Alkyl-Substituted Anilines Using a Palladium(I) Tri-tert-butylphosphine Bromide Dimer. J. Org. Chem. 2003, 68 (3), 1163-1164.

Sunggak Kim.; Chang Ho Oh.; Jae Suk Ko.; Kyo Han Ahn.; Yong Jin Kim. Zinc-modified cyanoborohydride as a selective reducing agent. J. Org. Chem. 1985, 50 (11), 1927-1932.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H315-H319-H335

Toxic if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P301+P310-P305+P351+P338-P304+P340-P362-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2209864
Harmonized Tariff Code
2921.42
TSCA
Yes

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