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Has synthetic applications of gold-catalyzed ring expansions. Development of novel type of transition metal-catalyzed cascade reactions utilizing small ring systems and the applications.
Jan. Rocek,; Annette E. Radkowsky.Mechanism of the chromic acid oxidation of cyclobutanol. J. Am. Chem. Soc. 1973 , 95(21),7123-7132.
Jan Rocek,; Annette E. Radkowsky.The role of chromium(IV) in oxidations by chromic acid. The oxidative cleavage of cyclobutanol. J. Am. Chem. Soc.1968 , 90(11), 2986-2988.
Gefahrenhinweise (EU): H225
Highly flammable liquid and vapour.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Dispose of contents/container in accordance with local/regional/national/international regulations.