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103-63-9 - (2-Bromoethyl)benzene, 98% - Phenethyl bromide - 2-Phenylethyl bromide - A12528 - Alfa Aesar

A12528 (2-Bromoethyl)benzene, 98%

CAS-Nummer
103-63-9
Synonyme
Phenethyl bromide
2-Phenylethyl bromide

Größe Preis ($) Menge Verfügbarkeit
100g 24,39
500g 81,55
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(2-Bromoethyl)benzene, 98%

MDL
MFCD00000240
EINECS
203-130-8

Chemische Eigenschaften

Formel
C8H9Br
Molmasse
185.06
Schmelzpunkt
-56°
Siedepunkt
220-221°
Flammpunkt
89°(192°F)
Dichte
1.355
Brechungsindex
1.5560
Löslichkeit
Miscible with ether and benzene. Immiscible with water.

Anwendungen

(2-Bromoethyl)benzene is used in the preparation of phenelzine by reacting with hydrazine. It is also used as a starting material to prepare various beta-phenethyl derivatives, active pharmaceutical ingredients, and fragrances. It finds application as a flame retardant.

Bemerkungen

Store in a cool place. Incompatible with strong oxidizing agents.

Literaturverweise

Shukla, P.; Sharma, A.; Pallavi, B.; Cheng, C. H. Nickel-catalyzed reductive Heck type coupling of saturated alkyl halides with acrylates and oxabenzonorbornadiene. Tetrahedron 2015, 71 (15), 2260-2266.

Huang, Y. B.; Yan, L.; Chen, M. Y.; Guo, Q. X.; Fu, Y. Selective hydrogenolysis of phenols and phenyl ethers to arenes through direct C-O cleavage over ruthenium-tungsten bifunctional catalysts. Green Chem. 2015, 17 (5), 3010-3017.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302-H315-H319-H335

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P362-P301+P312-P312-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
507487
Harmonized Tariff Code
2903.99
TSCA
Yes
RTECS
CY9032000

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