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122-04-3 - 4-Nitrobenzoyl chloride, 98% - A12543 - Alfa Aesar

A12543 4-Nitrobenzoyl chloride, 98%

CAS-Nummer
122-04-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
10g 15,39
250g 38,52
1000g 94,45
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4-Nitrobenzoyl chloride, 98%

MDL
MFCD00007345
EINECS
204-517-4

Chemische Eigenschaften

Formel
C7H4ClNO3
Molmasse
185.57
Schmelzpunkt
71-74°
Siedepunkt
155°/15mm
Flammpunkt
102°(215°F)
Dichte
1.53
Sensitivität
Moisture Sensitive
Löslichkeit
Soluble in terahydrofuran, dichloromethane, chloroform and pyridine.

Anwendungen

4-Nitrobenzoyl chloride is used in the preparation of polysubstituted furanonaphthoquinoines. It is also involved in Michael addition, Henry reaction, O-alkylation and cycloaddition reactions. Further, it is employed as an intermediate in active pharmaceutical ingredient and dyes.

Bemerkungen

Moisture sensitive. Incompatible with water, alcohols, oxidizing agents and strong bases.

Literaturverweise

Reagent for the preparation of crystalline esters.

Chen, W.; Feng, Y.; Zhang, M.; Wu, J.; Zhang, J.; Gao, X.; He, J.; Zhang, J. Homogeneous benzoylation of cellulose in 1-allyl-3-methylimidazolium chloride: Hammett correlation, mechanism and regioselectivity. RSC Adv. 2015, 5 (72), 58536-58542.

Skácel, J.; Budka, J.; Eigner, V.; Lhoták, P. Regioselective Friedel-Crafts acylation of calix[4]arenes. Tetrahedron 2015, 71 (13), 1959-1965.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Sicherheitshinweise: P280-P303+P361+P353-P305+P351+P338-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Weitere Referenzen

Merck
14,6590
Beilstein
473192
Gefahrenklasse
8
Verpackungsgruppe
II
Harmonized Tariff Code
2916.39
TSCA
Yes
RTECS
DM6651000

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