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2516-33-8 - Cyclopropanemethanol, 98% - Cyclopropyl carbinol - Cyclopropylmethanol - A12567 - Alfa Aesar

A12567 Cyclopropanemethanol, 98%

CAS-Nummer
2516-33-8
Synonyme
Cyclopropyl carbinol
Cyclopropylmethanol

Größe Preis ($) Menge Verfügbarkeit
5g 19,98
25g 51,40
100g 125,10
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Cyclopropanemethanol, 98%

MDL
MFCD00001309
EINECS
219-735-5

Chemische Eigenschaften

Formel
C4H8O
Molmasse
72.11
Schmelzpunkt
<-60°
Siedepunkt
123-124°
Flammpunkt
35°(95°F)
Dichte
0.904
Brechungsindex
1.4330
Löslichkeit
Fully miscible with water.

Anwendungen

Cyclopropanemethanol is used as an organic chemical synthesis intermediate.

Bemerkungen

Stable under recommended storage conditions. Incompatible with oxidizing agents and acid chlorides.

Literaturverweise

Lewis Brewster Young; Walter S.Trahanovsky. Cerium(IV) oxidation of organic compounds. III. Preparation of cyclopropanecarboxaldehyde from cyclopropanemethanol. J. Org. Chem. 1967, 32, (7)2349-2350

 

Yasunari Maeda; Takahiro Nishimura; Sakae Uemura. Vanadium-catalyzed isomerization of cyclopropanemethanols to homoallylic alcohols involving C-C bond cleavage. Chemistry Letters. 2005, 34, (3)380-381

For conversion to cyclobutene by tert-butoxide-induced elimination from cyclobutyl tosylate, see: Org. Synth. Coll., 7, 117 (1990).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H301-H311-H332-H319-H226-H373

Toxic if swallowed. Toxic in contact with skin. Harmful if inhaled. Causes serious eye irritation. Flammable liquid and vapour. May cause damage to organs through prolonged or repeated exposure.

Sicherheitshinweise: P210-P260-P261-P280-P301+P310-P303+P361+P353-P305+P351+P338-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1846846
Gefahrenklasse
3
Verpackungsgruppe
III
Harmonized Tariff Code
2906.19
TSCA
Yes
RTECS
GZ2212250

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