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615-13-4 - 2-Indanone, 98% - A12574 - Alfa Aesar

A12574 2-Indanone, 98%

CAS-Nummer
615-13-4
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 44,50
25g 171,00
100g 607,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

2-Indanone, 98%

MDL
MFCD00003792
EINECS
210-410-3

Chemische Eigenschaften

Formel
C9H8O
Molmasse
132.16
Schmelzpunkt
52-56°
Siedepunkt
218° dec.
Flammpunkt
100°(212°F)
Sensitivität
Hygroscopic
Löslichkeit
Insoluble in water.

Anwendungen

2-Indanone undergoes TiCl4-Mg mediated coupling with CHBr3 to yield dibromomethyl carbinol. It reacts with 5,5-dimethyl-3-pyrazolidinone to yield 5,5-dimethyl-2-(1H-indenyl-2)-3-pyrazolidinone. On photolysis by 266-nm one-photon excitation yields o-xylylene. It was used as starting reagent in the synthesis of indene-fused porphyrins.

Bemerkungen

Hygroscopic. Incompatible with oxidizing agents. Incompatible with oxidizing agents and bases.

Literaturverweise

Timothy D.Lash; Breland E.Smith; Michael J.Melquist; Bradley A.Godfrey. Synthesis of indenoporphyrins, highly modified porphyrins with reduced diatropic characteristics. Journal of Organic Chemistry. 2011, 76, (13)5335-5345

 

Tu-Hsin Yan; Su-Haur Chang; Cheng-Ta Chang; Chia-Kuan Lin; Chien-Yu Liu. Bromoform activation. TiCl4-Mg-promoted CHBr2- and CBr3- transfer to a variety of aldehydes and ketones. Organic Letters. 2013, 15, (22)5802-5805

GHS Gefahren- und Sicherheitshinweise

Sicherheitshinweise: P260u-P201-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
636550
Harmonized Tariff Code
2914.39
TSCA
Yes
RTECS
NK7535500

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