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It is a catalyst used in Stille reaction, hydrogenation reactions, Suzuki-Miyaura cross-coupling and Heck-Mizoroki reactions, deoxygenation, oxidation reactions and coupling reactions.
General-purpose hydrogenation catalyst suitable for a wide variety of applications. For a monograph, see: P. N. Rylander, Hydrogenation Methods, Academic Press, N.Y. (1985).
A large number of examples of hydrogenation reactions can be found in Organic Syntheses, although some of the earlier procedures may be somewhat outdated. A selection of rather more recent examples employing palladium on carbon include:
Hydrogenation of alkene to alkane: Org. Synth. Coll., 5, 97 (1973). Reduction of nitro to amine: Org. Synth. Coll., 5, 829 (1973). Reductive alkylation of amines: Org. Synth. Coll., 5, 552 (1973). Reduction of azide to amine: Org. Synth. Coll., 5, 586 (1973). High-pressure reduction of furan rings tetrahydrofurans: Org. Synth. Coll., 6, 856 (1988).
Perez-Lorenzo, M. Palladium Nanoparticles as Efficient Catalysts for Suzuki Cross-Coupling Reactions. J. Phys. Chem. Lett. 2012, 3 (2), 167-174.
Zhang, L. S.; Chen, G.; Wang, X.; Guo, Q. Y.; Zhang, X. S.; Pan, F.; Chen, K.; Shi, Z. J. Direct Borylation of Primary C H Bonds in Functionalized Molecules by Palladium Catalysis. Angew. Chem. 2014, 126 (15), 3980-3984.
Gefahrenhinweise (EU): H228
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves and eye/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: Special powder for metal fires.