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86-93-1 - 1-Phenyl-1H-tetrazole-5-thiol, 99% - 5-Mercapto-1-phenyl-1H-tetrazole - A12656 - Alfa Aesar

A12656 1-Phenyl-1H-tetrazole-5-thiol, 99%

CAS-Nummer
86-93-1
Synonyme
5-Mercapto-1-phenyl-1H-tetrazole

Größe Preis ($) Menge Verfügbarkeit
25g 34,51
100g 131,84
500g 418,40
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

1-Phenyl-1H-tetrazole-5-thiol, 99%

MDL
MFCD00003129
EINECS
201-710-5

Chemische Eigenschaften

Formel
C7H6N4S
Molmasse
178.22
Schmelzpunkt
ca 145° dec.
Flammpunkt
138°(280°F)
Sensitivität
Air Sensitive
Löslichkeit
Soluble in 5% ethanol, water (partly), acetone, chloroform, and methanol.

Anwendungen

1-Phenyl-1H-tetrazole-5-thiol is an effective inhibitor of aluminum corrosion in 1M HCl solution. 1-Phenyl-1H-tetrazole-5-thiol was used in the synthesis of oxacyclic building blocks via highly stereoselective radical cyclization and olefin metathesis reactions. It was also used in the synthesis of metalated tetradecyl sulfone. It is also used in the spectrophotometric determination of Pt and Bi.

Bemerkungen

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from oxidizing agents.

Literaturverweise

R Cea-Olivares.; OJ Sandoval.; G Espinosa-Perez. New organotin(IV) derivatives of 1-phenyl-1H-tetrazole-5-thiol. Crystal and molecular structure of 1?[Bz3SnSCN4Ph], a polymer built through secondary intermolecular Sn?N bonds. Polyhedron. 2008, 13, (19), 2809-2818.

C Ma.; J Sun. Hydrogen bonding and π-π stacking interaction in the coordination of sulfur and nitrogen donor heterocycle to organotin(IV): syntheses and crystal structures of di- and triorganotin(IV) derivatives with 1-(4-hydroxyphenyl)-1H-tetrazole-5-thiol. Polyhedron. 2004, 23, (9), 2809-2818.

In combination with t-butyl isocyanide, promotes the lactonization of long-chain hydroxy acids: Angew. Chem. Int. Ed., 20, 771 (1981).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H228

Flammable solid.

Sicherheitshinweise: P210-P280-P240-P241-P370+P378a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.

Weitere Referenzen

Beilstein
139068
Gefahrenklasse
4.1
Verpackungsgruppe
III
Harmonized Tariff Code
2933.99
TSCA
Yes
RTECS
XF7700000

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