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75-26-3 - 2-Bromopropane, 99% - Isopropyl bromide - A12944 - Alfa Aesar

A12944 2-Bromopropane, 99%

CAS-Nummer
75-26-3
Synonyme
Isopropyl bromide

Größe Preis ($) Menge Verfügbarkeit
250ml 42,20
1000ml 119,00
5000ml 445,00
Zum Warenkorb hinzufügen Zur Angebotsanfrage hinzufügen Artikel anzeigen

2-Bromopropane, 99%

MDL
MFCD00000147
EINECS
200-855-1

Chemische Eigenschaften

Formel
C3H7Br
Molmasse
123.00
Schmelzpunkt
-89°
Siedepunkt
59-60°
Flammpunkt
19°(66°F)
Dichte
1.310
Brechungsindex
1.4255
Löslichkeit
Miscible with alcohol, benzene, chloroform and ether. Slightly miscible with water and acetone.

Anwendungen

2-Bromopropane serves as an alkylating agent in organic synthesis. It is also used as an intermediate to form alkylated amines and alkylated metallic compounds. Further, it acts as a solvent for industrial cleaning, degreasing, metal processing and finishing, electronics, aerospace and aviation, aerosols, textiles, adhesives and inks. In addition, it is used for introducing the isopropyl functional group in organic synthesis.

Bemerkungen

Avoid all possible sources of ignition.Incompatible with strong oxidizing agents and strong bases.

Literaturverweise

Can be used, (K2CO3 in DMF), to protect phenolic OH groups as their isopropyl ethers, more stable than benzyl ethers to Lewis acids: J. Chem. Soc., Perkin 1, 2593 (1979).

Vatsal, A.; Zinjarde, S. S.; Kumar, A. R. Yarrowia lipolytica NCIM 3589, a tropical marine yeast, degrades bromoalkanes by an initial hydrolytic dehalogenation step. Biodegradation 2015, 26 (2), 127-138.

Simonetti, S. O.; Larghi, E. L.; Kaufman, T. S. Alternate and Step-Economic Synthesis of the β-Methylstyrene Chelating Pre-ligand of the Hoveyda-Grubbs’ II Catalyst. Org. Prep. Proced. Int. 2015, 47 (3), 227-231.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H360-H373

Highly flammable liquid and vapour. May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure.

Sicherheitshinweise: P210-P260-P201-P280-P281-P240-P241-P303+P361+P353-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,5210
Beilstein
741852
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2903.39
TSCA
Yes
RTECS
TX4111000

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