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104-54-1 - Cinnamyl alcohol, 98% - 3-Phenyl-2-propen-1-ol - A13025 - Alfa Aesar

A13025 Cinnamyl alcohol, 98%

CAS-Nummer
104-54-1
Synonyme
3-Phenyl-2-propen-1-ol

Größe Preis ($) Menge Verfügbarkeit
250g 31,83
1000g 81,13
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Cinnamyl alcohol, 98%

MDL
MFCD00002921
EINECS
203-212-3

Chemische Eigenschaften

Formel
C9H10O
Molmasse
134.18
Schmelzpunkt
32-35°
Siedepunkt
257-258°
Flammpunkt
126°(258°F)
Dichte
1.044
Löslichkeit
Soluble in water 1.8 g/L (20°C).

Anwendungen

Cinnamyl alcohol is an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. It is also used in perfumery and as well as a deodorant.

Bemerkungen

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Incompatible with strong oxidizing agents.

Literaturverweise

E Armengol.; ML Cano.; A Corma.; H García. Mesoporous aluminosilicate MCM-41 as a convenient acid catalyst for Friedel-Crafts alkylation of a bulky aromatic compound with cinnamyl alcohol. Journal of the Chemical Society, Chemical Communications.19957 (1), 519-520.

RL Mansell.; GG Gross.; J Stöckigt.; H Franke.; MH Zenk. Purification and properties of cinnamyl alcohol dehydrogenase from higher plants involved in lignin biosynthesis. Phytochemistry. 19747 (1), 519-520.

Protection of carboxylic acids as cinnamyl esters has been reported: J. Chem. Soc., Chem. Commun., 707 (1996). They can be cleaved under neutral conditions with Hg(II) or KSCN: Tetrahedron Lett., 2081 (1977).

Allylic alcohols react with primary or secondary amines in the presence of SnCl2 and a Pd(0) catalyst to give allylic amines regioselectively: Chem. Lett., 1121 (1995):

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H302-H315-H319-H317

Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction.

Sicherheitshinweise: P262-P280h-P305+P351+P338

Do not get in eyes, on skin, or on clothing. Wear protective gloves/clothing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Merck
14,2302
Beilstein
1903999
Harmonized Tariff Code
2906.29
TSCA
Yes
RTECS
GE2200000

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