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88-05-1 - 2,4,6-Trimethylaniline, 98% - Mesidine - 2-Aminomesitylene - A13049 - Alfa Aesar

A13049 2,4,6-Trimethylaniline, 98%

CAS-Nummer
88-05-1
Synonyme
Mesidine
2-Aminomesitylene

Größe Preis ($) Menge Verfügbarkeit
100g 36,67
500g 117,70
2500g 472,80
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2,4,6-Trimethylaniline, 98%

MDL
MFCD00007740
EINECS
201-794-3

Chemische Eigenschaften

Formel
C9H13N
Molmasse
135.21
Schmelzpunkt
-5°
Siedepunkt
232-234°
Flammpunkt
96°(204°F)
Dichte
0.962
Brechungsindex
1.5510
Löslichkeit
Slightly miscible with carbon tetrachloride. Immiscible with water.

Anwendungen

2,4,6-Trimethylaniline is useful for the preparation of Grubbs' catalyst. It is used as a precursor to dyes. It undergoes condensation reaction with glyoxal to prepare glyoxal-bis(mesitylimine). It is also involved in the preparation of 1,3-diketimines ligands by condensation with 1,3-diketones. Further, it is used for the production of Acid Blue 129 dye, which is useful in histochemistry studies. In addition to this, it serves as a building block to various bulky ligands.

Bemerkungen

Incompatible with strong oxidizing agents.

Literaturverweise

Samanta, R. C.; Yamamoto, H. Selective Halogenation Using an Aniline Catalyst. Chem. Eur. J. 2015, 21 (34), 11976-11979.

Kalden, D.; Krieck, S.; Görls, H.; Westerhausen, M. 1,3-Bis(2,4,6-trimethylphenyl)triazenides of potassium, magnesium, calcium, and strontium. Dalton Trans. 2015, 44 (17), 8089-8099.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H331-H302-H312-H315-H319-H335

Toxic if inhaled. Harmful if swallowed. Harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280-P305+P351+P338-P304+P340-P311-P362-P301+P312-P312-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
636559
Gefahrenklasse
6.1
Verpackungsgruppe
III
Harmonized Tariff Code
2921.49
TSCA
Yes
RTECS
BZ0700000

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