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1191-95-3 - Cyclobutanone, 98%, stab. with ca 0.01% BHT - A13068 - Alfa Aesar

A13068 Cyclobutanone, 98%, stab. with ca 0.01% BHT

CAS-Nummer
1191-95-3
Synonyme

Größe Preis ($) Menge Verfügbarkeit
1g 57,90
5g 217,80
25g 797,60
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Cyclobutanone, 98%, stab. with ca 0.01% BHT

MDL
MFCD00001332
EINECS
214-745-6

Chemische Eigenschaften

Formel
C4H6O
Molmasse
70.09
Schmelzpunkt
-51°
Siedepunkt
97-99°
Flammpunkt
10°(50°F)
Dichte
0.935
Brechungsindex
1.4210
Löslichkeit
Immiscible with water.

Anwendungen

Cyclobutanone is used in preparation of cyclobutane derivatives. It is used as a starting material for aminocyclobutanecarboxylic acid through sulfonyloxiranes. It is also used to prepare dihydro-furan-2-one in presence of polystyrene-bound phenylselenic acid as catalyst. Further, it is involved in the photochemical synthesis of nucleoside analogues such as bicyclic nucleosides and isonucleosides.

Bemerkungen

Store in a cool place. Incompatible with strong oxidizing agents, strong bases and strong reducing agents.

Literaturverweise

Lumbroso, A.; Catak, S.; Sulzer-Mosse, S.; Mesmaeker, A. D. Efficient access to functionalized cyclobutanone derivatives using cyclobuteniminium salts as highly reactive Michael acceptors. Tetrahedron Lett. 2015, 56 (19), 2397-2401.

Souillart, L.; Cramer, N. Regiodivergent Cyclobutanone Cleavage: Switching Selectivity with Different Lewis Acids. Chem. Eur. J. 2015, 21 (5), 1863-1867.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225

Highly flammable liquid and vapour.

Sicherheitshinweise: P210-P403

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Store in a well-ventilated place.

Weitere Referenzen

Beilstein
1560289
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2914.29
TSCA
Yes

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