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625-98-9 - 1-Chloro-3-fluorobenzene, 99% - 3-Chlorofluorobenzene - A13123 - Alfa Aesar

A13123 1-Chloro-3-fluorobenzene, 99%

CAS-Nummer
625-98-9
Synonyme
3-Chlorofluorobenzene

Größe Preis ($) Menge Verfügbarkeit
25g 43,09
100g 121,88
500g 442,40
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1-Chloro-3-fluorobenzene, 99%

MDL
MFCD00000569
EINECS
210-919-0

Chemische Eigenschaften

Formel
C6H4ClF
Molmasse
130.55
Siedepunkt
126-128°
Flammpunkt
20°(68°F)
Dichte
1.224
Brechungsindex
1.4940
Löslichkeit
Not miscible in water.

Anwendungen

1-Chloro-3-fluorobenzene used as medicine and liquid crystal intermediates.

Bemerkungen

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Literaturverweise

M.Onda; T.Odaka; H.Miyazaki; M. Mori; I.Yamaguchi; Y.Niide. Microwave Spectrum, Quadrupole Coupling Constant Tensors, and Dipole Moments of 1-Chloro-3-Fluorobenzene. Journal of Molecular Spectroscopy. 1994, 165, (2),426-432

 

Antonio Ramirez; John Candler; Crystal G.Bashore; Michael C.Wirtz, Jotham W.Coe; David B.Collum. Formation of benzynes from 2,6-dihaloaryllithiums: mechanistic basis of the regioselectivity. Journal of the American Chemical Society. 2004, 126, (45),14700-14701

Can be lithiated with n-BuLi at the 2-position. Reaction of the metallated species with CO2 gives 2-chloro-6-fluorobenzoic acid in 93% yield: Tetrahedron Lett., 37, 6551 (1996).

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H332-H315-H319-H335

Highly flammable liquid and vapour. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2039303
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2903.99
TSCA
Yes

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