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96-33-3 - Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol - Acrylic acid methyl ester - Methyl propenoate - A13128 - Alfa Aesar

A13128 Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol

CAS-Nummer
96-33-3
Synonyme
Acrylic acid methyl ester
Methyl propenoate

Größe Preis ($) Menge Verfügbarkeit
100ml 14,94
500ml 26,82
2500ml 68,19
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Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol

MDL
MFCD00008627
EINECS
202-500-6

Chemische Eigenschaften

Formel
CH2=CHCO2CH3
Molmasse
86.09
Schmelzpunkt
-75°
Siedepunkt
79-81°
Flammpunkt
-3°(26°F)
Dichte
0.956
Brechungsindex
1.4030
Sensitivität
Light Sensitive
Löslichkeit
Miscible with water.

Anwendungen

Methyl acrylate is a monomer used in the preparation of polymers having rigid, flexible, ionic, nonionic, hydrophobic, or hydrophilic properties. It is involved in the production of acrylate fiber, which is used to weave synthetic carpets. It plays an important role as a reagent in the synthesis of pharmaceutical intermediates and alfa ω-dicarboxylic acid esters. It is a good nucleophile and a michael acceptor to prepare polyamidoamine (PAMAM) dendrimers.

Bemerkungen

Light sensitive. Incompatible with oxidizing agents and peroxides.

Literaturverweise

Dai, S.; Sui, X.; Chen, C. Highly Robust Palladium(II) α-Diimine Catalysts for Slow-Chain-Walking Polymerization of Ethylene and Copolymerization with Methyl Acrylate. Angew. Chem. Int. Ed. 2015, 54 (34), 9948-9953.

Xia, G.; Jiang, X.; Zhou, L.; Liao, Y.; Wang, H.; Pu, Q.; Zhou, J. Synergic effect of methyl acrylate and N-cetylpyridinium bromide in N-cetyl-3-(2-methoxycarbonylvinyl) pyridinium bromide molecule for X70 steel protection. Corros. Sci. 2015, 94, 224-236.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H302-H312-H332-H315-H319-H317-H335

Highly flammable liquid and vapour. Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. May cause respiratory irritation.

Sicherheitshinweise: P210-P261-P280-P240-P303+P361+P353-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Merck
14,6011
Beilstein
605396
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2916.12
TSCA
Yes
RTECS
AT2800000

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