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A convenient method for the direct ɑ-methylenation of ketones involving reaction with formaldehede, in the presence of N-Methylanilinium trifluoroacetate, A17781, is illustrated for this ketone: Org. Synth. Coll., 7, 332 (1990)./n
Reacts with arenes under Friedel-Crafts conditions to give 6-aryl-1-tetralones: J. Org. Chem., 55, 4036 (1990)./n
The use of the selective reduction system in liquid ammonia is illustrated by the clean reduction of 1-tetralone to the alcohol without over-reduction to tetralin or reduction of the aromatic ring: J. Org. Chem., 61, 1493 (1996)./n
Gefahrenhinweise (EU): H302
Harmful if swallowed.
Wash thoroughly after handling. Do not eat, drink or smoke when using this product. IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. Dispose of contents/container in accordance with local/regional/national/international regulations.