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A13650 1,5-Hexadiene, 98%

CAS-Nummer
592-42-7
Synonyme
Biallyl
Diallyl

Stock No. Größe Preis ($) Menge Verfügbarkeit
A13650-14 25g 27,90
A13650-22 100g 70,00
A13650-36 500g 267,00
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1,5-Hexadiene, 98%

MDL
MFCD00008666
EINECS
209-754-7

Chemische Eigenschaften

Formel
CH2=CHCH2CH2CH=CH2
Molmasse
82.15
Schmelzpunkt
-141°
Siedepunkt
58-60°
Flammpunkt
-27°(-16°F)
Dichte
0.692
Brechungsindex
1.4040
Storage & Sensitivity
Ambient temperatures.
Löslichkeit
Soluble in water(0.17g/L).

Anwendungen

1,5-Hexadiene is used to study the Pd(II)-catalyzed cycloisomerization of functionalized 1,5-hexadienes.

Bemerkungen

Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Literaturverweise

Geoffrey W. Coates.; Robert M. Waymouth. Enantioselective cyclopolymerization of 1,5-hexadiene catalyzed by chiral zirconocenes: a novel strategy for the synthesis of optically active polymers with chirality in the main chain. J. Am. Chem. Soc. 1993, 115, (1), 91-98.

Anne Lise Mogstad.; Robert M. Waymouth. Chain transfer to aluminum in the homogeneous cyclopolymerization of 1,5-hexadiene. Macromolecules. 1992, 25, (8), 2282-2284.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H225-H319-H335-H304

Highly flammable liquid and vapour. Causes serious eye irritation. May cause respiratory irritation. May be fatal if swallowed and enters airways.

Sicherheitshinweise: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: Immediately call a POISON CENTER/doctor IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
1731106
Gefahrenklasse
3
Verpackungsgruppe
II
Harmonized Tariff Code
2901.29
TSCA
Yes
RTECS
MM1997800

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