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4595-60-2 - 2-Bromopyrimidine, 98+% - A13791 - Alfa Aesar

A13791 2-Bromopyrimidine, 98+%

CAS-Nummer
4595-60-2
Synonyme

Größe Preis ($) Menge Verfügbarkeit
5g 74,10
25g 277,00
100g 1050,00
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2-Bromopyrimidine, 98+%

MDL
MFCD00014601
EINECS
224-993-7

Chemische Eigenschaften

Formel
C4H3BrN2
Molmasse
158.99
Schmelzpunkt
53-57°
Siedepunkt
62-64°/1.5mm
Löslichkeit
Miscible with water.

Anwendungen

2-Bromopyrimidine is used in the preparation of 2,7-bis(2-pyrimidyl)-9,9-dihexylfluorene by cross-coupling with 9,9-dihexylfluorene-2,7-diboronic acid. It undergoes microwave-assisted aminocarbonylation at C-2 with palladium and molybdenum hexacarbonyl.

Bemerkungen

Store in a cool place. Incompatible with strong oxidizing agents, strong acids, acid chlorides.

Literaturverweise

Lu, X.; Wang, H.; Gao, R.; Pei, C. One-pot Metal-free Synthesis of Benzyl Alkyl Sulfides. Phosphorus Sulfur Silicon Relat Elem 2015, 190 (1), 45-52.

Huang, R.; Huang, Y.; Lin, X.; Rong, M.; Weng, Z. Well-Defined Copper(I) Fluoroalkoxide Complexes for Trifluoroethoxylation of Aryl and Heteroaryl Bromides. Angew. Chem. Int. Ed. 2015, 54 (19), 5736-5739.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
605945
Harmonized Tariff Code
2933.59
TSCA
Yes

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