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2?-(2-Fluorobenzylidene)-2-hydroxybenzohydrazide was synthesized by the reaction of 2-hydroxybenzoylhydrazine with 2-fluorobenzaldehyde in ethanol. Synthesis of n-aryl indolines from 2-fluorobenzaldehyde dimethylhydrazone derivatives which is an approach to preparation of c(aryl)-n(amine) bond atropisomeric amines. The o-dialkylaminobenzaldehydes were conveniently prepared by nucleophilic displacement of the activated fluorine in 2-fluorobenzaldehyde with the required dialkylamine in hot dimethylformamide. N?-(2-Fluorobenzylidene)-2-(quinolin-8-yloxy) acetohydrazide methanol solvate in the reaction of quinolin-8-yloxyacetic acid hydrazide and 2-fluorobenzaldehyde.
Ted Schaefer,; Craig S. Takeuchi. Computations and measurements of the structures and conformations of 2- and 3-fluorobenzaldehyde in the gas and in solution. Canadian Journal of Chemistry,1990, 68(2), 339-345.
Mino, Takashi; Tanaka, Youichi; Hattori, Youtaro; Tanaka, Motoko; Sakamoto, Masami; Fujita, Tsutomu. Synthesis of N-Aryl Indolines from 2-Fluorobenzaldehyde Dimethylhydrazone Derivatives: Approach to Preparation of C(aryl)-N(Amine) Bond Atropisomeric Amines. Letters in Organic Chemistry. 2004, 1 (1), 67-69(3).
Gefahrenhinweise (EU): H226-H302-H315-H319-H335
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