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589-87-7 - 1-Bromo-4-iodobenzene, 98% - 4-Bromoiodobenzene - A13859 - Alfa Aesar

A13859 1-Bromo-4-iodobenzene, 98%

CAS-Nummer
589-87-7
Synonyme
4-Bromoiodobenzene

Größe Preis ($) Menge Verfügbarkeit
10g 37,90
50g 143,04
250g 457,60
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1-Bromo-4-iodobenzene, 98%

MDL
MFCD00001051
EINECS
209-662-7

Chemische Eigenschaften

Formel
C6H4BrI
Molmasse
282.91
Schmelzpunkt
89-93°
Siedepunkt
252°
Sensitivität
Light Sensitive
Löslichkeit
Insoluble in water.

Anwendungen

It is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone. It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids).

Bemerkungen

Light sensitive. Store in a cool, dry, well-ventilated area. Store away from oxidizing agent, light.

Literaturverweise

Shenlin Huang; James M. Tour. Rapid bi-directional synthesis of oligo(1, 4-phenylene ethynylene)s. Tetrahedron Letters. 1999, 40 (17), 3447-3450.

Harry A.J. Oonk; Peter R. van der Linde; Jan Huinink; Jacobus G. Blok. Representation and assessment of vapour pressure data; a novel approach applied to crystalline 1-bromo-4-chlorobenzene, 1-chloro-4-iodobenzene, and 1-bromo-4-iodobenzene. J. Chem. Thermodyn. 1998, 30 (7), 897-907.

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Weitere Referenzen

Beilstein
1904545
Harmonized Tariff Code
2903.99
TSCA
Yes

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Kürzlich angesehen

Chemikalien

Life science

Metalle und Stoffe

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Forschungs- und Laborbedarf