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5824-40-8 - Tritylamine, 98% - Triphenylmethylamine - A13864 - Alfa Aesar

A13864 Tritylamine, 98%

CAS-Nummer
5824-40-8
Synonyme
Triphenylmethylamine

Größe Preis ($) Menge Verfügbarkeit
1g 22,70
5g 73,90
25g 258,00
100g 922,00
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Tritylamine, 98%

MDL
MFCD00008047

Chemische Eigenschaften

Formel
(C6H5)3CNH2
Molmasse
259.35
Schmelzpunkt
100-104°
Siedepunkt
223°/14mm
Sensitivität
Air Sensitive
Löslichkeit
Soluble in chloroform, methanol. Insoluble in water.

Anwendungen

Triphenylmethylamine was used to prepare diamondoid porous organic salt.1 It was also used in preparation of N-tritylated β-amino alcohols, useful building blocks in organic synthesis. It is used in the preparation of trityl- cysteine analogs as inhibitors of human mitotic kinesin.

Bemerkungen

Air sensitive. Store in a cool, dry, well-ventilated area. Store away from oxidizing agent.

Literaturverweise

Atsushi Yamamoto; Tetsuya Hasegawa; Tomoya Hamada; Tomofumi Hirukawa; Ichiro Hisaki; Mikiji Miyata; Norimitsu Tohnai. Role-allocated combination of two types of hydrogen bonds towards constructing a breathing diamondoid porous organic salt. Chemistry: A European Journal. 2013, 19 (9), 3006-3016.

Sushil K. Sharma; Michael F. Songster; Tracey L. Colpitts; Peter Hegyes; George Barany; Francis J. Castellino. Reductive amination with tritylamine as an ammonia equivalent: efficient preparation of the 5-(4-(9-fluorenylmethyloxycarbonyl)aminomethyl-3,5-dimethoxyphenoxy)valeric acid (PAL) handle for peptide synthesis. J. Org. Chem., 1993, 58 (18), 4993-4996.

Protected form of ammonia: the trityl group is removable by strong acid. For use in the synthesis of 1-aminoalkanephosphonic esters or acids, see: Synthesis, 370 (1988):

GHS Gefahren- und Sicherheitshinweise

Gefahrenhinweise (EU): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Sicherheitshinweise: P260u-P201-P280a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310a-P405-P501a

Obtain special instructions before use. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Weitere Referenzen

Beilstein
2113674
Harmonized Tariff Code
2921.45
TSCA
No

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